Catalysis in Ionic Liquids From Catalyst Synthesis to Application.pdf

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Published on 20 March 2014 on http://pubs.rsc.org | doi:10.1039/9781849737210-FP001
Catalysis in Ionic Liquids
From Catalyst Synthesis to Application
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RSC Catalysis Series
Series Editor:
Professor James J Spivey,
Louisiana State University, Baton Rouge, USA
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Published on 20 March 2014 on http://pubs.rsc.org | doi:10.1039/9781849737210-FP001
Advisory Board:
Krijn P de Jong,
University of Utrecht, The Netherlands
James A Dumesic,
University of Wisconsin-Madison, USA
Chris Hardacre,
Queen’s University Belfast, Northern Ireland
Enrique Iglesia,
University of California at Berkeley, USA
Zinfer Ismagilov,
Boreskov Institute of Catalysis, Novosibirsk, Russia
¨
Johannes Lercher,
TU Munchen, Germany
Umit Ozkan,
Ohio State University, USA
Chunshan Song,
Penn State University, USA
Titles in the Series:
1:
2:
3:
4:
5:
6:
7:
8:
9:
10:
11:
12:
13:
14:
15:
Carbons and Carbon Supported Catalysts in Hydroprocessing
Chiral Sulfur Ligands: Asymmetric Catalysis
Recent Developments in Asymmetric Organocatalysis
Catalysis in the Refining of Fischer–Tropsch Syncrude
Organocatalytic Enantioselective Conjugate Addition Reactions:
A Powerful Tool for the Stereocontrolled Synthesis of Complex Molecules
N-Heterocyclic
Carbenes: From Laboratory Curiosities to Efficient
Synthetic Tools
P-Stereogenic
Ligands in Enantioselective Catalysis
Chemistry of the Morita–Baylis–Hillman Reaction
Proton-Coupled Electron Transfer: A Carrefour of Chemical Reactivity
Traditions
Asymmetric Domino Reactions
C-H and C-X Bond Functionalization: Transition Metal Mediation
Metal Organic Frameworks as Heterogeneous Catalysts
Environmental Catalysis Over Gold-Based Materials
Computational Catalysis
Catalysis in Ionic Liquids: From Catalyst Synthesis to Application
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Catalysis in Ionic Liquids
From Catalyst Synthesis to Application
Downloaded on 12/04/2014 12:03:33.
Published on 20 March 2014 on http://pubs.rsc.org | doi:10.1039/9781849737210-FP001
Edited by
Chris Hardacre
Queen’s University Belfast, Northern Ireland
Email: c.hardacre@qub.ac.uk
Vasile Parvulescu
University of Bucharest, Romania
Email: vasile.parvulescu@g.unibuc.ro
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Published on 20 March 2014 on http://pubs.rsc.org | doi:10.1039/9781849737210-FP001
RSC Catalysis Series No. 15
ISBN: 978-1-84973-603-9
ISSN: 1757-6725
A catalogue record for this book is available from the British Library
r
The Royal Society of Chemistry 2014
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Preface
This book provides an up to date review of the state of the art of catalytic
reactions in ionic liquids as well as the formation of catalytic materials using
ionic liquid methods. Catalytic reactions were amongst the first to be
undertaken in these neoteric solvents with electrocatalytic studies being
reported in the 1960s. Thereafter, there has been an explosion in the interest
in this area starting with carbon–carbon bond forming reactions utilizing
ionic liquids as the catalyst as well as the solvent in Friedel–Crafts, Heck and
Diels–Alder reactions. From there the field moved onto study gas–liquid
reactions, asymmetric processes and the conversion of biomass. A wide
range of catalysts have been utilized and modified to be compatible with
ionic liquid processes including homogeneous complexes, nanoparticles,
supported metal heterogeneous catalysts, supported ionic liquid based
catalysts, zeolites, enzymes, electrocatalysts and photocatalysts. In the vast
majority of cases, the ionic liquid based processes have been compared with
analogous molecular derived systems with significant advantages being
demonstrated, for example, in rate, selectivity, recycle of the catalyst or work
up procedures. In a number of cases, the ionic liquid based systems have
enabled new reactions to be undertaken. Due to the wide range of ionic
liquids available and the ability to functionalise the cation and the anion to
tailor their physical and chemical properties, the field of catalysis in ionic
liquids has been transformed over the last 20 years from both the
perspective of novel materials synthesis as well as reactivity-selectivity
profiles. The chapters provide a perspective on how ionic liquid properties
can be modified by structural changes to enable the catalytic materials and
processes to be controlled. In addition, the reviews provide a summary of
where our understanding lies in these systems. The complex nature of the
interactions involved and the potential these systems have to change many
industrial processes provide significant opportunities for future study.
RSC Catalysis Series No. 15
Catalysis in Ionic Liquids: From Catalyst Synthesis to Application
Edited by Chris Hardacre and Vasile Parvulescu
r
The Royal Society of Chemistry 2014
Published by the Royal Society of Chemistry, www.rsc.org
v

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